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Synthesis, crystal structure and Third-order nonlinear optical properties of 4-N,N- dimethylamino -4’-N’- 9-methanoanthracene-stilbazolium tetraphenylborate
Qian Zhang 1 #,Liu Zhaodi 1,Liu Huijun 2,Wu Jieying 1,Zhou Hongpin 1,Yang Jiaxiang 2,Tian Yupeng 3 *
1.Department of Chemistry, Anhui Province Key Laboratory of Functional Inorganic Materials, Anhui University, Hefei 230039, P.R. China
2.Department of Chemistry, Anhui Province Key Laboratory of Functional Inorganic Materials, Anhui University
3.Department of Chemistry, Anhui Province Key Laboratory of Functional Inorganic Materials, Anhui University, Hefei 230039, P.R. China;State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, P. R. China.
*Correspondence author
#Submitted by
Subject:
Funding: 国家自然科学资金项目(No.No. 50532030, 50703001, 20771001)
Opened online:29 March 2010
Accepted by: none
Citation: Qian Zhang,Liu Zhaodi,Liu Huijun.Synthesis, crystal structure and Third-order nonlinear optical properties of 4-N,N- dimethylamino -4’-N’- 9-methanoanthracene-stilbazolium tetraphenylborate [OL]. [29 March 2010] http://en.paper.edu.cn/en_releasepaper/content/41244
 
 
A novel substituent styryl pyridinium tetraphenylborate, 4-N,N- dimethylamino -4’-N’- 9-methanoanthracene-stilbazolium tetraphenylborate, has been synthesized and characterized by IR spectrum and X-ray single-crystal diffraction. The complex crystallizes in monoclinic space group P21/c with a = 1.2557 (1) nm, b = 1.539(1) nm, c = 2.2202 (8) nm, β =101.099(1) °, and V = 4.2105(4) nm3, Z = 4, Dc = 1.159 g•cm-3. In the title molecule, the pyridyl ring of the cation makes dihedral angle of 2.8° with the phenyl ring. The nonlinear optical properties of the compound were investigated by virtue of 1064 nm nanosecond laser beam, and the results show that the novel pyridinium salt has a TPA coefficient of β= 0.028 cm/GW, a TPA cross-section of σ= 8.68×10-48 cm4•s•photon-1.
Keywords:Substituent styryl pyridinium salt;nonlinear optical property;crystal structure;Z-scan
 
 
 

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