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The Solubilities and Physicochemical Properties of the Aqueous Ternary System Containing Lithium, Rubidium and Borate Ions at 348 K
YU Xudong 1 #,ZENG Ying 1 *,LUO Yulin 2,ZHANG Yu 2,LIU Zhou 2
1.College of Materials and Chemistry & Chemical Engineering, Chengdu University of Technology, Chengdu 610059; Mineral Resources Chemistry Key Laboratory of Sichuan Higher Education Institutions, Chengdu 610059
2.College of Materials and Chemistry & Chemical Engineering, Chengdu University of Technology, Chengdu 610059
*Correspondence author
#Submitted by
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Funding: none
Opened online:12 January 2015
Accepted by: none
Citation: YU Xudong,ZENG Ying,LUO Yulin.The Solubilities and Physicochemical Properties of the Aqueous Ternary System Containing Lithium, Rubidium and Borate Ions at 348 K[OL]. [12 January 2015] http://en.paper.edu.cn/en_releasepaper/content/4626761
 
 
In this paper, the solubility values and physicochemical properties of electrolyte mixtures in ternary system containing lithium, rubidium and borate ions were studied at 348 K by isothermal dissolution method. The crystalloid forms of the solid phase were determined using a schreinermarks wet residue method. On the basis of the experimental data, the stable equilibrium phase diagram and the physicochemical properties vs composition in the ternary system at 348 K were plotted. The experimental results show that this system is of a simple eutectic type system, no double salt or solid solution formed at 348 K. The phase diagram consists of one invariant point, two uninvariant curves, and two crystallization regions. The crystallization regions correspond to lithium tetraborate trihydrate (Li2B4O7o3H2O) and rubidium pentaborate tetrahydrate (RbB5O6(OH) 4o2H2O). Salt Li2B4O7o3H2O has lager crystallization field, whereas salt RbB5O6(OH) 4o2H2O has smaller crystallization field.
Keywords:chemical thermodynamics; phase equilibrium; rubidium; borate; stable phase equilibrium
 
 
 

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