| |
| In order to gain improved understanding of the kinetics and dynamics of C, N, and O reaction with a solid surface, it is essential to focus on the reaction from the perspectives of bond formation, bond dissociation, bond relaxation, bond vibration, and the consequences on charge polarization and repopulation as well as the energetic response of the involved atoms and valence electrons. The sp-orbital hybridization is suggested necessary for the C,N, and O involved reactions with associations of anisotropic bonding and valence identities and the localized energy states of bonding pairs, nonbonding lone pairs, and the lone pair induced antibonding dipoles, as well as the hydrogen bond like and the C-H bond like states, which could unify the observations using atomistic microscopy, crystallography, electronic and vibronic spectroscopes, and provide guidelines for functional materials design. |
|
| Keywords:chemical reaction; surface; bond |
|
