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Palladium-catalyzed Hydrodechlorination of Ary Chlorides and its Mechanism
Chen Zhang,Xiaoyan Li,Hongjian Sun * #
Shandong University
*Correspondence author
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Funding: 教育部博士点基金（No.20050422011）
Opened online:20 January 2009
Accepted by: none
Citation: Chen Zhang,Xiaoyan Li,Hongjian Sun.Palladium-catalyzed Hydrodechlorination of Ary Chlorides and its Mechanism[OL]. [20 January 2009] http://en.paper.edu.cn/en_releasepaper/content/28087
 
 
Successful hydrodechlorinations of aryl chlorides were carried out in the presence of palladium catalyst supported by dppf and sodium formate in DMA (N, N-dimethylacetamide). A series of substituted aryl chlorides as substrates were studied to investigate the influence of electronic effects on the reaction. A proposed mechanism of hydrodechlorination via decarboxylation and hydrogen migration was discussed with the supported of in situ IR data.
Keywords:palladium;dechlorination;aryl chloride;in situ IR
 
 
 

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