Synthesis and electron-donating property of novel porphyrazines containing tetrathiacrown ether-linked tetrathiafulvalene moieties

Hou Ruibin; Jin Longyi; Yin Bingzhu

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Synthesis and electron-donating property of novel porphyrazines containing tetrathiacrown ether-linked tetrathiafulvalene moieties

Hou Ruibin *,Jin Longyi,Yin Bingzhu

Department of chemistry, Yanbian university

*Correspondence author

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Subject:

Funding: 国家自然科学基金,教育部博士点基金（No.20662010,20060184001）

Opened online:16 June 2009

Accepted by: none

Citation: Hou Ruibin ,Jin Longyi,Yin Bingzhu .Synthesis and electron-donating property of novel porphyrazines containing tetrathiacrown ether-linked tetrathiafulvalene moieties[OL]. [16 June 2009] http://en.paper.edu.cn/en_releasepaper/content/33170

Novel magnesium and metal-free porphyrazines (4 and 5) containing four peripheral tetrathiacrownether-linked tetrathiafulvalene moieties have been synthesized and characterized. Their solution electrochemical data showed two reductive and three oxidative processes within a −1500 mV to +1500 mV potential window. UV/Vis spectroscopy and electron paramagnetic resonance(EPR) measurements reveal the formation of a charge transfer complex between porphyrazine 4 with F4TCNQ. The single-crystal structure of the TTF-dicyanocrown ether 3 is presented.

Keywords:Porphyrazine;tetrathiafulvalene;crown ether;CT complex

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