Photoluminescent and electroluminescent properties of a novel europium(III) complex involving electron-transporting functional groups

Li Yu; Wang Yafei; Zhu Weiguo

Chinese︱Feedback︱Save this page

• Elaborating Academic Views 　　　　 • Exchanging Innovative Ideas
• Protecting Intellectual Properties 　　• Fast Sharing Science Papers

Sponsored by the Center for Science and Technology Development of the Ministry of Education
Supervised by Ministry of Education of the People's Republic of China

Home > Papers

Photoluminescent and electroluminescent properties of a novel europium(III) complex involving electron-transporting functional groups

Li Yu 1 #,Wang Yafei 2,Zhu Weiguo 2 *

1.Department of Chemistry, Xiangtan University, HuNan XiangTan 411105

2.Department of Chemistry, Xiangtan University

*Correspondence author

#Submitted by

Subject:

Funding: the New Teacher Fund and specialized Research Fund for the Doctoral Program of Higher Education（No.200805301013 and 20094301110004）, Support from the National Natural Science Foundation of China （No.20872124 and 21172187）

Opened online:16 January 2012

Accepted by: none

Citation: Li Yu,Wang Yafei,Zhu Weiguo.Photoluminescent and electroluminescent properties of a novel europium(III) complex involving electron-transporting functional groups[OL]. [16 January 2012] http://en.paper.edu.cn/en_releasepaper/content/4459065

A novel tris(dibenzoylmethanato)[5-(2-(4-tert-butylbenzenyl)-5-benzenyl-1,3,4-oxadiazole -4’)-1,10-phenanthroline]europium(III) [Eu(DBM)3(BuOXD-Phen)] containing an electron-transport- ing oxadiazole functionalized phenanthroline, was synthesized and characterized. Its UV-vis absorption and photoluminescence, as well as the electroluminescence in polymer light-emitting devices (PLEDs) were investigated. The double-layer PLEDs with a configuration of ITO/PEDOT:PSS (50 nm)/PVK (40 nm)/PFO:PBD (30%):Eu(DBM)3(BuOXDPhen) (1-8 wt %) (80 nm)/Ba (4 nm)/Al (150 nm) were fabricated. Saturated red europium(III) ion emission, based on the 5D0→7F2 transition, is centered at a wavelength of 614 nm with a full width at half maximum (FWHM) of 10 nm. The highest external quantum efficiency of 1.26% photons per electron at current density of 0.63 mA/cm2, with maximum brightness of 61.2 cd/m2 at 144.7 mA/cm2, was achieved in the double-layer PLEDs. The results indicate that an introduction of oxadiazole groups into phenanthroline ligand can improve the performance of its europium complex doped PLEDs.

Keywords:Europium(III) complex; Oxadiazole; Electroluminescence; Polymer light-emitting devices

For this paper

● PDF (0B)
● Revision 0 　　
● Print this paper
● Recommend this paper to a friend
● Add to my favorite list

Saved Papers

Please enter a name for this paper to be shown in your personalized Saved Papers list

Tags

Add yours

Related Papers

Statistics

PDF Downloaded	326
Bookmarked	0
Recommend	6
Comments	Array

Submit your papers

Alert Name:
Alerting to:
Authentication email will be sent to your email address in 24 hours
Frequency:
Email Message Format:	Plain text Graphical(HTML)

Complete the form below and we will recommend the selected titles to your friends on your behalf. * Indicates a required field.
Your name*:
Your email address*:
Recipient's name*:
Recipient's email address*:
(multiple recipient's names and email addresses should be separated with semicolons)
Your comments:	I thought you would find the page(s) useful.

Your name:
Your email address:
Recipient's name:
Recipient's email address:
(multiple recipient's names and email addresses should be separated with semicolons)
Your comments:	I thought you would find this page useful.

Disclaimer: This message was sent to your friend using the "Send it to a friend" facility on the Sciencepaper Online’ WWW site, http://www.paper.edu.cn/en. The Sciencepaper Online is not responsible for the content of this email, and anything said in this email does not necessarily reflect the Sciencepaper Online's views.

	Check out RSS, or use RSS reader to subscribe this item

Saved Papers