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Cooperation of π-π Interaction and Template Effect in Ionothermal Synthesis of Multi-Dimensional Manganese Naphthalene-1,4- Dicarboxylate Compounds
Huang Lin-Na,Meng Yan,Liu Jun-Liang,Tong Ming-Liang,Lin Zhuojia *
School of Chemistry and Chemical Engineering, Sun Yat-Sen University
*Correspondence author
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Funding: NSFC (No.Grant no. 20901084) and the Doctoral Fund of Ministry of Education of China for New Scholar)
Opened online: 9 March 2012
Accepted by: none
Citation: Huang Lin-Na,Meng Yan,Liu Jun-Liang.Cooperation of π-π Interaction and Template Effect in Ionothermal Synthesis of Multi-Dimensional Manganese Naphthalene-1,4- Dicarboxylate Compounds[OL]. [ 9 March 2012] http://en.paper.edu.cn/en_releasepaper/content/4467109
 
 
Two layered manganese naphthalene-1,4-dicarboxylate compounds based on the paddle-wheel Mn2(COO)4 motifs, (EMIm)[Mn(ndc)Br] and (HMIm)[Mn(ndc)Br], and two three-dimensional networks (RMIm)[Mn2(ndc)2(OAc)] (RMIm = BMIm and HMIm ) were prepared from various ionic liquids. Significant relationship of π-π interactions and template effect are found between the naphthalene part of organic ligands and IL imidazolium rings
Keywords:Ionothermal; π-π Interaction; Manganese
 
 
 

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