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Synthesis of a novel alkenyl oxime and its response to metal ions
Xu Haifeng,Zhong Hong,Wang Shuai * #
College of Chemistry and Chemical Engineering, Central South University, Changsha, 410083, China
*Correspondence author
#Submitted by
Subject:
Funding: the National High Technology Research and Development Program of China (No.863 Program, No. 2013AA064102), the Hunan Provincial Natural Science Foundation of China (No.No.11JJ6014), The Doctoral Fund of Ministry of Education of China (No.No.20100162120028)
Opened online:21 November 2013
Accepted by: none
Citation: Xu Haifeng,Zhong Hong,Wang Shuai.Synthesis of a novel alkenyl oxime and its response to metal ions[OL]. [21 November 2013] http://en.paper.edu.cn/en_releasepaper/content/4569822
 
 
A novel collector 2-ethyl-2-hexenal oxime was synthesized using 2-ethyl-2-hexenal and hydroxylamine hydrochloride as raw materials. The yield of oxime was above 78% under the optimum conditions. This product was characterized by elemental analysis, infrared spectrum, mass spectrum, and NMR spectroscopy. The results of ultraviolet spectrum showed that the oxime exhibited stronger reaction ability with Cu(II) than with Ni(II), Fe(III), Ag(I), Co(II) and Zn(II) ions. Infrared spectroscopic analysis implicated that the oxime bound to Cu(II) ions through C=C and C=N groups.
Keywords:synthesis; 2-ethyl-2-hexenal oxime; metal ions, coordination
 
 
 

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