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Catalytic Activity of Styrene-divinyl Benzene Supporting Metallophthalocyanine
Huang Xianwen,Yao Yuyuan #,Lv Wangyang,Wang Xiuhua,Chen Wenxing *
Zhejiang Sci-Tech University
*Correspondence author
#Submitted by
Subject:
Funding: 国家自然科学基金,国家自然科学基金,教育部博士点基金,浙江省自然科学基金（No.20574061,50872124,20060338002,Y4080341）
Opened online:10 October 2008
Accepted by: none
Citation: Huang Xianwen,Yao Yuyuan,Lv Wangyang.Catalytic Activity of Styrene-divinyl Benzene Supporting Metallophthalocyanine[OL]. [10 October 2008] http://en.paper.edu.cn/en_releasepaper/content/24698
 
 
Binuclear cobalt phthalocyanine (Co2Pc2) was supported on styrene-divinyl benzene resin by covalent bond to obtain a novel catalytic functional material, Resin-Co2Pc2. The effects of pH, the quantity of Resin-Co2Pc2 and temperature on the catalytic activity of Resin-Co2Pc2 on 2-mercaptoethanol were investigated. The results showed that Resin-Co2Pc2 had high catalytic activity on 2-mercaptoethanol, and even the catalytic activity was the best at pH11. The reaction can further be enhanced with the quantity of Resin-Co2Pc2 and temperature increasing, due to its endothermic characteristics. There was no decrease in the catalytic activity of Resin-Co2Pc2 after five repetitive experiments, which indicated that Resin-Co2Pc2 could be recycled.
Keywords:binuclear cobalt phthalocyanine;catalytic oxidation;functional materials;2-mercaptoethanol
 
 
 

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