The progress of acylase-catalyzed addition and its tandem reaction in organic media

Bokai Liu; Xianfu Lin

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The progress of acylase-catalyzed addition and its tandem reaction in organic media

Bokai Liu #,Xianfu Lin * #

Department of Chemistry, Zhejiang University

*Correspondence author

#Submitted by

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Funding: 教育部博士点基金（No.20060335031）

Opened online:12 January 2010

Accepted by: none

Citation: Bokai Liu,Xianfu Lin.The progress of acylase-catalyzed addition and its tandem reaction in organic media[OL]. [12 January 2010] http://en.paper.edu.cn/en_releasepaper/content/38827

Enzymatic promiscuity, namely the possibility that one active site of an enzyme can catalyze several different chemical transformations, has been paid more attention and valuable synthesis tool for synthetic chemistry. This mini-review will focus on promiscuous acylase-mediated reactions that are useful in organic synthesis. The examples of catalytic promiscuity in Michael addition, Markovnikov addition by acylase and cascade reaction for the synthesis of pyrimidine derivatives with sugar branch are reviewed.

Keywords:enzymatic promiscuous;acylase;Michael addition;Markovnikov addition

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