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Nucleophilic Dearomatization of Chloromethyl Naphthalene Derivatives via η3-Benzyl Palladium Intermediates: A New Strategy for Catalytic Dearomatization
PENG Bo 1,ZHANG Sheng 2,FENG Xiujuan 2,YU Xiaoqiang 2,BAO Ming 2 * #
1.State Key Laboratory of Fine Chemicals, Dalian University of Technology
2.State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024
*Correspondence author
#Submitted by
Subject:
Funding: The National Natural Science Foundation of China (No.Nos. 20972021 and 21072023), The Specialized Research Fund for the Doctoral Program of Higher Education (No.No. 20090041110012), The Program for Changjiang Scholars and Innovative Research Teams in Universities (No.No. IRT0711)
Opened online: 8 September 2011
Accepted by: none
Citation: PENG Bo,ZHANG Sheng,FENG Xiujuan.Nucleophilic Dearomatization of Chloromethyl Naphthalene Derivatives via η3-Benzyl Palladium Intermediates: A New Strategy for Catalytic Dearomatization[OL]. [ 8 September 2011] http://en.paper.edu.cn/en_releasepaper/content/4441734
 
 
Palladium-catalyzed nucleophilic dearomatization of chloromethyl naphthalene derivatives to produce ortho- or para-substituted carbocycles in satisfactory to excellent yields has been developed. The unprecedented dearomatization reactions proceeded smoothly under mild conditions via η3-benzyl palladium intermediates.
Keywords:Organic chemistry; nucleophilic dearomatization; naphthalene derivative; η3-benzyl palladium
 
 
 

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