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Sponsored by the Center for Science and Technology Development of the Ministry of Education
Supervised by Ministry of Education of the People's Republic of China
The Zeeman energy splitting or the external magnetic field effect on the temperature induced spin relaxation in organic semiconductors is investigated. By numerical solving the Liouville equations of a four-level system with energy level fluctuation, we show that the relaxation processes of spin singlet state of a coupled polaron pair are not affected by the Zeeman splitting. The magnetic field has small effect on the spin relaxation of T0 spin triplet state. But for the other spin triplet states with parallel spins, the relaxation processes will have periodic oscillation around the saturation value in present of magnetic field. The period and the amplitude of oscillation depend on the values of Zeeman splitting. The application of the model on understanding the organic magnetic field effect is also dicusssed.