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Iron-Catalyzed Friedel-Crafts Allylation of Aromatics with Allylic Alcohols and Acetate
HE Chao,ZHANG Shuting,XIONG Yan * #
School of Chemistry and Chemical Engineering, Chongqing University, 400030 Chongqing, China
*Correspondence author
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Funding: The Specialized Research Fund for the Doctoral Program of Higher Education （No.No. 20120191120041）
Opened online:26 March 2014
Accepted by: none
Citation: HE Chao,ZHANG Shuting,XIONG Yan.Iron-Catalyzed Friedel-Crafts Allylation of Aromatics with Allylic Alcohols and Acetate[OL]. [26 March 2014] http://en.paper.edu.cn/en_releasepaper/content/4590759
 
 
Iron-catalyzed allylation of aromatics with allylic alcohols and acetate is presented. FeCl3•6H2O has proved to be an effective catalyst for this transformation. A variety of aromatic compounds are coupled with allylic reagents to furnish the corresponding 1, 3-disubstituted propenes in moderate to high yields under mild conditions. The catalytic cycle mechanism as a Friedel-Crafts process is illustrated in the assistance of ultraviolet spectrum analysis
Keywords:Friedel-Crafts allylation; allylic reagents; aromatics; FeCl3•6H2O
 
 
 

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