Synthesis and Phase Structures of Bent-Core Mesogen-Jacketed Liquid Crystalline Diblock Copolymers

Chen Xiaofang; Zhou Qifeng

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Synthesis and Phase Structures of Bent-Core Mesogen-Jacketed Liquid Crystalline Diblock Copolymers

Chen Xiaofang 1 * #,Zhou Qifeng 2

1.Peking Uinversity

2.Peking University

*Correspondence author

#Submitted by

Subject:

Funding: 教育部博士点基金（No.20030001061）

Opened online:17 October 2006

Accepted by: none

Citation: Chen Xiaofang ,Zhou Qifeng .Synthesis and Phase Structures of Bent-Core Mesogen-Jacketed Liquid Crystalline Diblock Copolymers[OL]. [17 October 2006] http://en.paper.edu.cn/en_releasepaper/content/8789

A series of diblock copolymers with polystyrene as coil segment and bent-core mesogen-jacketed liquid crystalline polymer as rigid segment were synthesized via sequential atom transfer radical polymerization. SAXS and WAXD studies revealed that these rod-coil blocks packed together forming a layer structure, with the rod axes parallel to the lamellar normal. Within the lamellar structure, PVC14 rods packed with high hexagonal order.

Keywords: diblock copolyemrs, liquid crystalline polymers, bent-core mesogens

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