Liquid Crystalline Poly(meth)acrylates Containing Bent-Core Mesogens: Synthesis and Characterization

Chen Xiaofang; Zhou Qifeng

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Liquid Crystalline Poly(meth)acrylates Containing Bent-Core Mesogens: Synthesis and Characterization

Chen Xiaofang * #,Zhou Qifeng

Peking University

*Correspondence author

#Submitted by

Subject:

Funding: 教育部博士点基金（No.20030001061）

Opened online: 9 November 2006

Accepted by: none

Citation: Chen Xiaofang ,Zhou Qifeng.Liquid Crystalline Poly(meth)acrylates Containing Bent-Core Mesogens: Synthesis and Characterization[OL]. [ 9 November 2006] http://en.paper.edu.cn/en_releasepaper/content/9419

Side chain liquid crystalline (LC) poly(meth)acrylates with end-on bent-core liquid crystalline (BCLC) mesogens were synthesized. The resulting polymers exhibit thermotropic LC behavior. SmCP phases were observed for both monomers and polymers. In LC monomers, typical antiferroelectric switching was observed. In the corresponding polymers, a unique bilayer structure was observed, which is different from the reported BCLC bilayer SmCG phase.

Keywords:liquid crystalline polymers, bent-core mesogens, antiferroelectricity

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