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Thermodynamic assessment of the LiCl-LiH-LiI system
GUO Cuiping 1 * #,DU Zhenmin 2,LI Changrong 3
1.School of Materials Science and Engineering,University of Science and Technology Beijing, Beijing 100083
2.School of Materials Scicence and Engineering,University of Science and Technology Beijing, Beijing, 100083
3.School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing, 100083
*Correspondence author
#Submitted by
Subject:
Funding: The National Doctorate Fund of the State Education Ministry of China （No.No. 20090006120029）
Opened online:23 October 2012
Accepted by: none
Citation: GUO Cuiping,DU Zhenmin,LI Changrong.Thermodynamic assessment of the LiCl-LiH-LiI system[OL]. [23 October 2012] http://en.paper.edu.cn/en_releasepaper/content/4488493
 
 
The LiCl-LiH, the LiH-LiI. the LiCl-LiI, and the LiCl-LiH-LiI systems were critically assessed by means of the CALPHAD technique. The liquid phase was described by the two sublattice model, (Li+)(Cl-,H-,I-). The end-member-based solid solution LiCl, LiH and LiI with the same structure was modeled as the formula Li(Cl,H,I). On the basis of experimental phase diagram information and thermodynamic data, the phase diagram of the LiCl-LiH, the LiH-LiI. the LiCl-LiI system and five vertical sections and one liquidus surface projection in the LiCl-LiH-LiI systems were optimized using Thermo-Calc software, and a set of self-consistent thermodynamic parameters of the LiCl-LiH-LiI system was obtained.
Keywords:Phase diagram; LiCl-LiH-LiI ternary system; CALPHAD technique
 
 
 

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