Highly Luminescent Hierarchical Architectures of Lanthanide-Based Complexes

LIU Nijuan; BU Weifeng

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Highly Luminescent Hierarchical Architectures of Lanthanide-Based Complexes

LIU Nijuan 1,BU Weifeng 2 * #

1.Key Laboratory of Nonferrous Metals Chemistry and Resources Utilization of Gansu Province and College of Chemistry and Chemical Engineering, Lanzhou University, LanZhou 730000

2.Key Laboratory of Nonferrous Metals Chemistry and Resources Utilization of Gansu Province and College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000

*Correspondence author

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Funding: The Specialized Research Fund for the Doctoral Program of Higher Education （No.20100211110023）

Opened online:19 April 2013

Accepted by: none

Citation: LIU Nijuan,BU Weifeng.Highly Luminescent Hierarchical Architectures of Lanthanide-Based Complexes[OL]. [19 April 2013] http://en.paper.edu.cn/en_releasepaper/content/4537623

In this paper,we report the preparation of lanthanide(III)-based metallogelators by cationic surfactant (DODA, DODA = dimethyl dioctadecyl ammonium) and lanthanide complexes [Ln(dpa)3]3- (Ln = Eu, Tb; dpa = dipicolinate) and their hierarchical self-assembly into highly luminescent flower-like and giant vesicular architectures in organic solvents, respectively. The present concept suggests that the combination of lanthanide(III) complexes with stepwise molecular self-assembly will open an alternative methodology to develop lanthanide(III)-based sensors and optoelectronic materials.

Keywords:Lanthanide(III) complexes; Luminescence; Vesicles; Metallogels; Self-assembly

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