Asymmetric Phase-Transfer-Catalyzed 1,6-Conjugate Addition of Thiols to in situ Generated para-Quinone Methides

ZHOU Lei; FAN Yajing; LI Shen

Chinese︱Feedback︱Save this page

• Elaborating Academic Views 　　　　 • Exchanging Innovative Ideas
• Protecting Intellectual Properties 　　• Fast Sharing Science Papers

Sponsored by the Center for Science and Technology Development of the Ministry of Education
Supervised by Ministry of Education of the People's Republic of China

Home > Papers

Asymmetric Phase-Transfer-Catalyzed 1,6-Conjugate Addition of Thiols to in situ Generated para-Quinone Methides

ZHOU Lei,FAN Yajing,LI Shen * #

Department of Chemistry, School of Science, Tianjin University, Tianjin 300354

*Correspondence author

#Submitted by

Subject:

Funding: the Specialized Research Fund for the Doctoral Program of Higher Education of China （No.No. 20130032120071）

Opened online:10 May 2017

Accepted by: none

Citation: ZHOU Lei,FAN Yajing,LI Shen.Asymmetric Phase-Transfer-Catalyzed 1,6-Conjugate Addition of Thiols to in situ Generated para-Quinone Methides[OL]. [10 May 2017] http://en.paper.edu.cn/en_releasepaper/content/4732205

A catalytic asymmetric 1,6-conjugate addition of thiols to in situ generated para-quinone methides has been developed, affording a range of optically active benzyl thioethers in excellent yields and enantioselectivities. The use of para-hydroxybenzyl sulfones as precursors for the formation of transient p-QM intermediates allows to overcome the limitations in substrate scope.

Keywords:Asymmetric catalysis; Phase-transfer catalysis; 1,6-Conjugate addition; para-quinone methide

For this paper

● PDF (0B)
● Revision 0 　　
● Print this paper
● Recommend this paper to a friend
● Add to my favorite list

Saved Papers

Please enter a name for this paper to be shown in your personalized Saved Papers list

Tags

Add yours

Related Papers

Statistics

PDF Downloaded	24
Bookmarked	0
Recommend	0
Comments	Array

Submit your papers

Alert Name:
Alerting to:
Authentication email will be sent to your email address in 24 hours
Frequency:
Email Message Format:	Plain text Graphical(HTML)

Complete the form below and we will recommend the selected titles to your friends on your behalf. * Indicates a required field.
Your name*:
Your email address*:
Recipient's name*:
Recipient's email address*:
(multiple recipient's names and email addresses should be separated with semicolons)
Your comments:	I thought you would find the page(s) useful.

Your name:
Your email address:
Recipient's name:
Recipient's email address:
(multiple recipient's names and email addresses should be separated with semicolons)
Your comments:	I thought you would find this page useful.

Disclaimer: This message was sent to your friend using the "Send it to a friend" facility on the Sciencepaper Online’ WWW site, http://www.paper.edu.cn/en. The Sciencepaper Online is not responsible for the content of this email, and anything said in this email does not necessarily reflect the Sciencepaper Online's views.

	Check out RSS, or use RSS reader to subscribe this item

Saved Papers