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1. Decarboxylative (4+1) Oxidative Annulation of Malonate Monoesters with 2-Vinylpyridine Derivatives | |||
TANG Shan,GAO Xinlong,LEI Aiwen | |||
Chemistry 03 June 2016 | |||
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Abstract:A novel N-iodosuccinimide mediated decarboxylative (4+1) oxidative annulation between 2-vinylpyridine derivatives and malonate monoesters was developed. It offered a new way to construct indolizines derivatives by utilizing malonate monoesters as C1 unit. Alkyl 2,2-diiodoacetate was found to be the active reaction intermediate during the transformation. | |||
TO cite this article:TANG Shan,GAO Xinlong,LEI Aiwen. Decarboxylative (4+1) Oxidative Annulation of Malonate Monoesters with 2-Vinylpyridine Derivatives[OL].[ 3 June 2016] http://en.paper.edu.cn/en_releasepaper/content/4695660 |
2. Pd(II)-Catalysed Monoarylation of 2-Phenylpyridine N-Oxides with Iodobenzene in Water | |||
Zhang Wei,Zhou Xiangge | |||
Chemistry 20 May 2016 | |||
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Abstract:A Pd(II)-catalysed activation and arylation of C(sp2)-H bond directed by pyridine N-oxide in water is achieved with high regioselectivity to form monoarylated products in yields up to 91%. The wide substrate scope highlights the flexibility of the catalyst.The reaction mechanism is proposed. | |||
TO cite this article:Zhang Wei,Zhou Xiangge. Pd(II)-Catalysed Monoarylation of 2-Phenylpyridine N-Oxides with Iodobenzene in Water[OL].[20 May 2016] http://en.paper.edu.cn/en_releasepaper/content/4691373 |
3. Diastereo- and Enantioselective Aldol Reaction of Isocyanoacetates with Aldehydes Catalyzed by Chiral Phase-Transfer Catalysts | |||
DIAO Ruichuan,LI Shen | |||
Chemistry 29 April 2016 | |||
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Abstract:A diastereo- and enantioselective aldol reaction of tert-butyl isocyanoacetate with aldehydes was realized under metal-free phase-transfer catalytic conditions. Key to success was the use of a free 9-OH-containing cinchona alkaloid-based quaternary ammonium salt bearing bulky and electron-withdrawing aryl groups on the N-benzyl moiety. This process tolerates both aromatic and aliphatic aldehydes, affording the corresponding chiral oxazoline products in diastereoselectivities up to 20:1 and enantioselectivities up to 78% ee. | |||
TO cite this article:DIAO Ruichuan,LI Shen. Diastereo- and Enantioselective Aldol Reaction of Isocyanoacetates with Aldehydes Catalyzed by Chiral Phase-Transfer Catalysts[J]. |
4. Intermolecular 1,3-Dipolar Cycloaddition Reactions of Chiral Cyclic Nitrones with Alkenes | |||
LUO Yongchun,CHENG Ruiling,XU Pengfei | |||
Chemistry 27 November 2015 | |||
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Abstract:A efficient 1,3-dipolar cycloaddition reaction between the new chiral cyclic nitrones and alkenes was studied. After the optimization of reaction conditions, a series of valuable chiral isoxazolidine products were prepared with high yields. The structre of the products was characterized by NMR, IR and HR Ms. In addition, according to the analysis of the reaction's transition state, the stereoselevtivity of this cycloaddition and the absolute configuration of cycloadducts was explained reasonably. | |||
TO cite this article:LUO Yongchun,CHENG Ruiling,XU Pengfei. Intermolecular 1,3-Dipolar Cycloaddition Reactions of Chiral Cyclic Nitrones with Alkenes[OL].[27 November 2015] http://en.paper.edu.cn/en_releasepaper/content/4665101 |
5. Synthesis and photophysical properties of star-shaped fluorescent molecules composed of 1, 3, 5-triphenoxybenzene core and triarylamine terminals | |||
WANG Baolin,XU Taoshan,SHAO Xiangfeng | |||
Chemistry 16 November 2015 | |||
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Abstract:A series of star-shaped fluorescent molecules (2-5), employing 1,3,5-triphenoxybenzene as core and triarylamine as terminal groups, were synthesized through a facile three-step approach. The stability, solid state structure, and photophysical properties of 2-5 were investigated. In comparison with pristine triphenylamine, the present star-shaped compounds display the strong fluorescence with high fluorescence quantum yields up to 81.8 %. Besides, the influence of the aryls on the electronic properties of the resulting star-shaped molecules has been evaluated. | |||
TO cite this article:WANG Baolin,XU Taoshan,SHAO Xiangfeng. Synthesis and photophysical properties of star-shaped fluorescent molecules composed of 1, 3, 5-triphenoxybenzene core and triarylamine terminals[OL].[16 November 2015] http://en.paper.edu.cn/en_releasepaper/content/4661199 |
6. Concise Total Synthesis of (±)- Pisiferin | |||
Yulong Li,Liqi Li,Yueming Guo,Zhixiang Xie | |||
Chemistry 02 April 2015 | |||
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Abstract:A concise total synthesis of (±)-pisiferin has been accomplished from α-cycloiral via Suzuki coupling and F-C alkylation as key reaction in five steps with an overall yield of 16%. The feature of this concise strategy is using acetyl group to protect the phenol which could be deprotection in moderate condition to avoid the isomerization of target molecular. This work not only provides a strategy to approach the total synthesis of pisiferin itself but also serves as an additional correlation origin to which many related icetaxane-type diterpenes can be referred. | |||
TO cite this article:Yulong Li,Liqi Li,Yueming Guo, et al. Concise Total Synthesis of (±)- Pisiferin[OL].[ 2 April 2015] http://en.paper.edu.cn/en_releasepaper/content/4636172 |
7. Three-component Synthesis of Homoallylic Amines Catalyzed by Phosphomolybdic Acid Supported on Silica Gel | |||
XIE Zhengfeng,WANG Jide | |||
Chemistry 11 March 2013 | |||
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Abstract:Phosphomolybdic acid supported on silica gel (PMA/SiO2) has been used for the catalysis of the three-component reactions of aldehydes, amines and allyltributylstannane with acetonitrile as the solvent at room temperature. The experimental parameters were optimized in the three-component reaction system. The obtained results showed the PMA/SiO2 showed its highly efficient nature for catalyzing the three-component reactions. were not found to induce a obvious reduction in the yield of the corresponding allylation reaction, regardless of aromatic aldehydes and amines containing electron-donating or electron-withdrawing groups in the aromatic ring that involve in the three-component reaction with Aromatic amines or aldehydes and allyltributylstannane. Our results indicated that this synthetic process has advantages of high yield, mild reaction conditions, environment benign and easy manipulation. | |||
TO cite this article:XIE Zhengfeng,WANG Jide. Three-component Synthesis of Homoallylic Amines Catalyzed by Phosphomolybdic Acid Supported on Silica Gel[OL].[11 March 2013] http://en.paper.edu.cn/en_releasepaper/content/4526296 |
8. Mechanism Analysis for Catalytic Synthesis of 4-quinolones Derivatives by Eaton's reagent | |||
Liu Tianyu,Qiao Yuanyuan | |||
Chemistry 28 July 2012 | |||
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Abstract:For its impressive antibiotic activity, Eaton's reagent has been extensively used to catalyze the synthesis of 4-quinolone derivatives, but the mechanism behind the reaction is still not clear till now. In this paper, a possible mechanism for this reaction is revealed by using the density functional theory (DFT) method, which is consistent with the experimental phenomenon, and the existing main and side reactions are also explained successfully. | |||
TO cite this article:Liu Tianyu,Qiao Yuanyuan. Mechanism Analysis for Catalytic Synthesis of 4-quinolones Derivatives by Eaton's reagent[OL].[28 July 2012] http://en.paper.edu.cn/en_releasepaper/content/4485283 |
9. Total Synthesis of threo-(2S,3R)-3-(4-Hydroxy-3,5-dimethoxyphenyl)-3-ethoxypropane-1,2-diol | |||
XIA Yamu,LIU Haixin,DAI Xiaoli | |||
Chemistry 25 July 2012 | |||
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Abstract:Ficus beecheyana's rhizomes have long been used as a folk medicine to treat rheumatism and diabetes. threo-(2S,3R)-3-(4-Hydroxy-3,5-dimethoxyphenyl)-3-ethoxypropane-1,2-diol was isolated from the roots of this plant. In the paper, the asymmetric synthesis of threo-(2S,3R)-3-(4-Hydroxy-3,5- dimethoxyphenyl)-3-ethoxypropane-1,2-diol was reported for the first time, and based on the asymmetric dihydroxylation as a key reaction. The target compound was obtained through six steps. | |||
TO cite this article:XIA Yamu,LIU Haixin,DAI Xiaoli. Total Synthesis of threo-(2S,3R)-3-(4-Hydroxy-3,5-dimethoxyphenyl)-3-ethoxypropane-1,2-diol[OL].[25 July 2012] http://en.paper.edu.cn/en_releasepaper/content/4485197 |
10. Synthesis of polyhalo 2-aryl-4-aminoquinazolines and 3-amino-1H-indazoles as anticancer agents | |||
Yan Shengjiao,Dong Ying,Peng Qiong,Fan Yingxian,He Nengqin,Zhang Jihong*,Lin Jun* | |||
Chemistry 29 March 2012 | |||
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Abstract:A series of polyhalo 2-aryl-4-aminoquinazolines 3a~3n were prepared by reacting polyhalo isophthalonitriles 1a~1c with amidine hydrochlorides under basic conditions with good yields (70~93%). Similarly, through the reaction of polyhalo isophthalonitriles 1a~1c with hydrazines to give some novel polyhalo 3-aminoindazoles 5 and 7 with moderate yield (70~87%). The anticancer activities of compounds 3, 5 and 7 were evaluated in vitro against human cell lines SkOV-3, HeLa, U2-OS, A549, and MCF-7. Some compounds showed excellent growth inhibitory activity and 3a was found to be the most potent active molecular, with an IC50 value lower than 3.86 μg/mL against the five tumor cell lines. | |||
TO cite this article:Yan Shengjiao,Dong Ying,Peng Qiong, et al. Synthesis of polyhalo 2-aryl-4-aminoquinazolines and 3-amino-1H-indazoles as anticancer agents[OL].[29 March 2012] http://en.paper.edu.cn/en_releasepaper/content/4473518 |
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